Champions League 2025/26: Outright Betting & Matchday 4 Preview
The opening phase of the 2025/26 Champions League reaches the halfway stage during the first week in November.
Matchday 4 features some eye-catching fixtures, many of which will have a significant bearing on the race to progress to the last-16 of the competition.
Read on as we look at the latest betting for the Champions League, before previewing what promises to be a thrilling fourth round of matches.
Champions League 2025/26 – Betting
Leading online sportsbook Betway rates reigning champions Paris Saint-Germain as the favourites to retain the title.
Here are the latest outright odds:
Paris Saint-Germain – 9/2
Arsenal – 5/1
Barcelona – 11/2
Liverpool – 7/1
Bayern Munich – 15/2
Real Madrid – 9/1
Manchester City – 10/1
Chelsea – 20/1
Inter Milan – 28/1
Newcastle United – 28/1
Tottenham Hotspur – 40/1
Borussia Dortmund – 50/1
Napoli – 50/1
Atletico Madrid – 50/1
Juventus – 100/1
Galatasaray – 125/1
Atalanta – 150/1
Athletic Club – 150/1
Bayer Leverkusen – 150/1
Marseille – 150/1
Monaco – 150/1
PSV Eindhoven – 150/1
Eintracht Frankfurt – 200/1
Sporting CP – 200/1
Villarreal – 250/1
Club Brugge – 400/1
Ajax – 500/1
Benfica – 500/1
Olympiakos – 500/1
Bodo/Glimt – 1000/1
FC Copenhagen – 1000/1
FK Qarabag – 1000/1
Pafos FC – 1000/1
Slavia Prague – 1000/1
Union Saint-Gilloise – 1000/1
Kairat Almaty – 2000/1
Champions League 2025/26 – Matchday 4 Preview
Tuesday, November 4
Slavia Prague vs Arsenal
Napoli vs Eintracht Frankfurt
Atletico Madrid vs Union Saint-Gilloise
Bodo/Glimt vs Monaco
Juventus vs Sporting CP
Liverpool vs Real Madrid
Olympiacos vs PSV Eindhoven
Paris Saint-Germain vs Bayern Munich
Tottenham Hotspur vs FC Copenhagen
Wednesday, November 5
Pafos FC vs Villarreal
Qarabag vs Chelsea
Ajax vs Galatasaray
Club Brugge vs Barcelona
Inter Milan vs Kairat Almaty
Manchester City vs Borussia Dortmund
Newcastle United vs Athletic Club
Marseille vs Atalanta
Benfica vs Bayer Leverkusen
Five teams have a 100 per cent record after the first three matches, but that is guaranteed to change when PSG and Bayern Munich meet in France.
PSG recorded an impressive 7-2 victory at Bayer Leverkusen on their most recent outing to take their tally to 13 goals in the competition this season.
However, Bayern are undoubtedly a much tougher nut to crack. They have made a stellar start to the 2025/26 campaign and could cause PSG plenty of problems.
Real Madrid’s unbeaten record will be sternly tested when they head to Merseyside to take on Premier League champions Liverpool.
Madrid edged past Juventus in their last game to maintain their perfect record, while Liverpool ran out 5-1 winners at Eintracht Frankfurt.
The Reds have won four and drawn one of their previous 12 meetings with the La Liga giants and will be eager to improve that record at Anfield.
Arsenal visit Slavia Prague bidding to make it four consecutive victories in the Champions League and they are a good bet to achieve the feat.
They dismantled Atletico Madrid at the Emirates Stadium on Matchday 3 and should have too much firepower for the Czechia side.
Inter Milan should also maintain their unbeaten record when they face Kairat Almaty at the San Siro. The Kazakhstani side look out of their depth at this level.
The clash between Manchester City and Borussia Dortmund at the Etihad Stadium could be pivotal to their respective hopes of securing a top eight finish.
Man City have been functional rather than spectacular in this season’s competition, but have still picked up seven points out of a possible nine.
They will be tested by Dortmund, who are the joint-second highest scorers in the competition alongside Bayern with 12 goals.
The English club have lost just one of the previous six meetings with Dortmund, but would be well advised not to underestimate the threat they pose.
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